An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation.

نویسندگان

  • Elena Arceo
  • Peter Marsden
  • Robert G Bergman
  • Jonathan A Ellman
چکیده

An efficient 1,2-deoxygenation method, involving an unexpected mechanism, was found for simple diols and for biomass-derived polyols (glycerol and erythritol) that results in the conversion of the 1,2-dihydroxy group to a carbon-carbon double bond.

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عنوان ژورنال:
  • Chemical communications

دوره 23  شماره 

صفحات  -

تاریخ انتشار 2009